Methacrylic acid
Hazard Statements
| Code | Statement | Hazard Class |
|---|---|---|
H227 |
Combustible liquid | Flammable liquids |
H302 |
Harmful if swallowed | Acute toxicity, oral |
H311 |
Toxic in contact with skin | Acute toxicity, dermal |
H314 |
Causes severe skin burns and eye damage | Skin corrosion/irritation |
H318 |
Causes serious eye damage | Serious eye damage/eye irritation |
H335 |
May cause respiratory irritation | Specific target organ toxicity, single exposure; Respiratory tract irritation |
H372 |
Causes damage to organs through prolonged or repeated exposure | Specific target organ toxicity, repeated exposure |
H373 |
May causes damage to organs through prolonged or repeated exposure | Specific target organ toxicity, repeated exposure |
Precautionary Statements
| Code | Statement |
|---|---|
P210 |
Keep away from heat, hot surface, sparks, open flames and other ignition sources. No smoking. |
P260 |
Do not breathe dust/fume/gas/mist/vapors/spray. |
P261 |
Avoid breathing dust/fume/gas/mist/vapors/spray. |
P262 |
Do not get in eyes, on skin, or on clothing. |
P264 |
Wash hands [and ...] thoroughly after handling. |
P264+P265 |
Wash hands [and ...] thoroughly after handling. Do not touch eyes. |
P270 |
Do not eat, drink or smoke when using this product. |
P271 |
Use only outdoors or in a well-ventilated area. |
P280 |
Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... |
P301+P317 |
IF SWALLOWED: Get medical help. |
P301+P330+P331 |
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. |
P302+P352 |
IF ON SKIN: wash with plenty of water/... |
P302+P361+P354 |
IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. |
P304+P340 |
IF INHALED: Remove person to fresh air and keep comfortable for breathing. |
P305+P354+P338 |
IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. |
P316 |
Get emergency medical help immediately. |
P317 |
Get emergency medical help. |
P319 |
Get medical help if you feel unwell. |
P321 |
Specific treatment (see information on this label and safety datasheet)). |
P330 |
Rinse mouth. |
P361+P364 |
Take off immediately all contaminated clothing and wash it before reuse. |
P363 |
Wash contaminated clothing before reuse. |
P370+P378 |
In case of fire: Use ... to extinguish. |
P403 |
Store in a well-ventilated place. |
P403+P233 |
Store in a well-ventilated place. Keep container tightly closed. |
P405 |
Store locked up. |
P501 |
Dispose of contents/container to ... |
Exposure Limits
| NIOSH REL | 20 ppm |
| Skin Notation | Yes — can be absorbed through skin |
Physical Properties
Colorless liquid or solid (below 61°F) with an acrid, repulsive odor.
| Boiling Point | 325°F |
| Flash Point | 171°F (open-cup) |
| Vapor Pressure | 0.7 mmHg |
| Specific Gravity | 1.015 at 68°F |
NFPA 704 Diamond
2
3
2
Health
Fire
Reactivity
Target Organs
severe eye and skin irritation
Synonyms
methacrylic acid (glacial); methacrylic acid (inhibited); α-methacrylic acid; 2-methylacrylic acid; 2-methylpropenoic acid
Data Sources
- GHS Classification: PubChem CID 4093
- NIOSH REL/IDLH: NIOSH Pocket Guide
Disclaimer: This information is compiled from public regulatory databases for reference only. It does not replace the manufacturer's Safety Data Sheet (SDS). Always consult the official SDS for your specific product before handling chemicals.
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