Hydrogen fluoride

CAS 7664-39-3 HF (aqueous) MW 20.0000 Danger
Gas Cylinder Gas Cylinder
Corrosion Corrosion
Skull and Crossbones Skull and Crossbones
Health Hazard Health Hazard
Emergency: 911 | Poison Control: 1-800-222-1222

Safety Data Sheets

ManufacturerDownload
Acros Organics Download PDF
Alfa Aesar Download PDF
Sigma Aldrich Download PDF

Hazard Statements

CodeStatementHazard Class
H280 Contains gas under pressure; may explode if heated Gases under pressure
H314 Causes severe skin burns and eye damage Skin corrosion/irritation
H318 Causes serious eye damage Serious eye damage/eye irritation
H331 Toxic if inhaled Acute toxicity, inhalation
H370 Causes damage to organs Specific target organ toxicity, single exposure
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure
H402 Harmful to aquatic life Hazardous to the aquatic environment, acute hazard

Precautionary Statements

CodeStatement
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands [and ...] thoroughly after handling.
P264+P265 Wash hands [and ...] thoroughly after handling. Do not touch eyes.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P361+P354 IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.
P308+P316 IF exposed or concerned: Get emergency medical help immediately.
P316 Get emergency medical help immediately.
P317 Get emergency medical help.
P319 Get medical help if you feel unwell.
P321 Specific treatment (see information on this label and safety datasheet)).
P363 Wash contaminated clothing before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P501 Dispose of contents/container to ...

Exposure Limits

OSHA PEL3 ppm
NIOSH REL3 ppm (Ceiling: 6 ppm)
NIOSH IDLH30 ppm
Skin NotationYes — can be absorbed through skin

Physical Properties

Colorless gas or fuming liquid (below 67°F) with a strong, irritating odor.

Boiling Point67°F
Vapor Pressure783 mmHg
Specific Gravity1

NFPA 704 Diamond

0
4
1
Health Fire Reactivity

Target Organs

Lungs Skin

skin, eye, and airway irritation; bone effects

Synonyms

anhydrous hydrofluoric acid, HF-A

Data Sources

Disclaimer: This information is compiled from public regulatory databases for reference only. It does not replace the manufacturer's Safety Data Sheet (SDS). Always consult the official SDS for your specific product before handling chemicals.

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